Polymorphic transformations in iodine titanium

نویسندگان

چکیده

Based on the analysis of differential scanning calorimetry data, possibility classifying observed endothermic or exothermic transformations as phase first oder is considered. Two approaches have been implemented. The based correspondence between temperatures maximum conversion rate and extrema second derivative signal with respect to temperature. In approach, transformation considered a kind kinetic reaction chemical process determination some parameters included in equations. this case, order parameter such n obtained from shape region registration temperatures. Using example experiments carried out during thermal cycling titanium iodide samples, it shown that both make possible fairly adequately attribute processes cause calorimetric effects dependences first-order transitions. particular, results heating cooling show polymorphic are realized by various mechanisms depending history metal. Keywords: activation energy, titanium, calorimetry, polymorphism, structure, approximation.

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ژورنال

عنوان ژورنال: Fizika tverdogo tela

سال: 2022

ISSN: ['0367-3294', '1726-7498']

DOI: https://doi.org/10.21883/pss.2022.11.54208.400